I have to agree with Aubrey regarding the voice-changing as being a "movie thing". I've been reading the series to my son over the past couple of months, and we just finished GoF. Nothing was mentioned in CoS or GoF regarding voice changes. The only thing in CoS mentioned was Harry not needing his glasses when he had changed into Crabbe (or Goyle, I can't remember), noticing Ron's hair changing back to red and his nose lengthening, and Harry not being able to see well once he had returned to his regular self (before he put his glasses back on).
And in DH when the 6 other "Harry's" are taking the polyjuice potion the real Harry was kind of freaked out when he was saw 6 people that looked and sounded like him. And when Hermione used it to become Bellatrix the DE she met in Diagon Alley didn't notice anything different about her voice. I think Ron had to disguise his voice but that was because he had been transfigured.
But back to GoF...

, It was definitely Moody/Crouch making the polyjuice potion on his own. When Harry saw "Barty Crouch" on the Marauder's Map that was him stealing ingredients from Snape's office. Later at the end, when DD has given Barty Jr Veritaserum, Barty Jr admits he was taking the ingredients from Snape's office:
QUOTE
I also needed his {Moody's} hair to make the Polyjuice Potion. The other ingredients were easy. I stole boomslang skin from the dungeons. When the Potions master found me in his office, I said I was under orders to search it. (pg 689 US Hardback edition)